Synthesis CuInSe2 (CISe) Thin Films Prepared from Metal-Ethanolamine Complex Compound

Ersan Y Muslih, Agus Ismail, Kyoo Ho Kim

Abstract


CuInSe2 (CISe) thin film was successfully fabricated from copper and indium salts with ethanolamine as precursors. All of these precursors were dissolved and formed complex compounds with ethanolamine simultaneously which deposited on soda lime glass by spin coating at 200 rpm, followed by heat treatment in the ambient atmosphere at 200oC for 120 minutes and finally selenization at 550oC using selenium pellets under Ar (95%) + H2 (5%) for 120 minutes to fabricate CISe thin film. Reaction mechanism, structure, morphology and chemical composition also reported in this work.


Keywords


Synthesis CuInSe2, Ethanolamine as precursors; Complex compounds; Selenium pellets

Full Text:

PDF

References


Araujo, J., Ortiz, R., López-Rivera, A., Ortega, J. M., Montilla, M., & Alarcón, D. (2007). Electrochemical growth of CuInSe2 thin film on different substrates from alkaline medium. Characterization of the films. Journal of Solid State Electrochemistry, 11(3), 407-412.

Cho, A., Song, H., Gwak, J., Eo, Y. J., Yun, J. H., Yoon, K., & Ahn, S. (2014). A chelating effect in hybrid inks for non-vacuum-processed CuInSe 2 thin films. Journal of Materials Chemistry A, 2(14), 5087-5094.

Hibberd, C. J., Chassaing, E., Liu, W., Mitzi, D. B., Lincot, D., & Tiwari, A. N. (2010). Non‐vacuum methods for formation of Cu (In, Ga)(Se, S) 2 thin film photovoltaic absorbers. Progress in Photovoltaics: Research and Applications, 18(6), 434-452.

Liu, Y., Kong, D., Li, J., Zhao, C., Chen, C., & Brugger, J. (2012). Preparation of Cu (In, Ga) Se2 Thin Film by Solvothermal and Spin-coating Process. Energy Procedia, 16, 217-222.

Rehan, S., Kim, K. Y., Han, J., Eo, Y. J., Gwak, J., Ahn, S. K., ... & Ahn, S. (2016). Carbon-Impurity Affected Depth Elemental Distribution in Solution-Processed Inorganic Thin Films for Solar Cell Application. ACS applied materials & interfaces, 8(8), 5261-5272.

Shay, J. L., Tell, B., Kasper, H. M., & Schiavone, L. M. (1973). Electronic Structure of AgIn Se 2 and CuIn Se 2. Physical Review B, 7(10), 4485.




DOI: http://dx.doi.org/10.17509/ijost.v2i2.8018

DOI (PDF): http://dx.doi.org/10.17509/ijost.v2i2.8018.g5056

Refbacks

  • There are currently no refbacks.


Copyright (c) 2017 Ersan Y Muslih, Agus Ismail, Kyoo Ho Kim

Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.

Lisensi Creative Commons

Indonesian Journal of Science and Technology is published by UPI Press. This work is licensed under a Creative Commons Attribution-Sharealike 4.0.

StatCounter - Free Web Tracker and Counter View My Stats