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Corncob-Derived Sulfonated Magnetic Solid Catalyst Synthesis as Heterogeneous Catalyst in The Esterification of Waste Cooking Oil and Bibliometric Analysis


 
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1. Title Title of document Corncob-Derived Sulfonated Magnetic Solid Catalyst Synthesis as Heterogeneous Catalyst in The Esterification of Waste Cooking Oil and Bibliometric Analysis
 
2. Creator Author's name, affiliation, country Primata Mardina; Lambung Mangkurat University; Indonesia
 
2. Creator Author's name, affiliation, country Hesti Wijayanti; Lambung Mangkurat University; Indonesia
 
2. Creator Author's name, affiliation, country Rinna Juwita; Lambung Mangkurat University; Indonesia
 
2. Creator Author's name, affiliation, country Meilana Dharma Putra; Lambung Mangkurat University; Indonesia
 
2. Creator Author's name, affiliation, country Iryanti Fatyasari Nata; Lambung Mangkurat University; Indonesia
 
2. Creator Author's name, affiliation, country Rowina Lestari; Konkuk University; Korea, Republic of
 
2. Creator Author's name, affiliation, country Muhammad Faqih Al-Amin; Lambung Mangkurat University; Indonesia
 
2. Creator Author's name, affiliation, country Regi Abizar Suciagi; Lambung Mangkurat University; Indonesia
 
2. Creator Author's name, affiliation, country Oktefani Kusuma Rawei; Lambung Mangkurat University; Indonesia
 
2. Creator Author's name, affiliation, country Liza Lestari; Lambung Mangkurat University; Indonesia
 
3. Subject Discipline(s)
 
3. Subject Keyword(s) Corncob; Impregnation; Magnetic; Solid acid catalyst; Sulfonation
 
4. Description Abstract A corncob-derived magnetic solid acid catalyst was synthesized through the sulfonation method and an impregnation process, respectively. In the sulfonation process, the concentrated H2SO4 was utilized as an activation agent to obtain acidic properties. The solution of ferric sulphate-ferrous sulphate was utilized for impregnation to generate the magnetic behaviour of the material. The prepared magnetic acid solid catalyst had a high saturation magnetisation value of 16.48 emu/g and a total acidity of 1.43 mmol/g. The performance of the catalyst was evaluated in the esterification reaction of waste cooking oil. The best result presented 86.12% FFA conversion under reaction conditions of 5% catalyst loading and a 1:15 oil-to-methanol molar ratio at 60oC for 4 h. The catalyst was separated magnetically from the reaction solution and exhibited a good reusability with 61% remaining active after 5 consecutive cycles of reaction. This study resulted in a promising method to obtain magnetic-sulfonated carbon-based catalyst from corncob residue, and it is economical potentially and environmentally friendly for the esterification of low-quality feedstock for biodiesel production.
 
5. Publisher Organizing agency, location Universitas Pendidikan Indonesia
 
6. Contributor Sponsor(s)
 
7. Date (YYYY-MM-DD) 2023-11-09
 
8. Type Status & genre Peer-reviewed Article
 
8. Type Type
 
9. Format File format PDF
 
10. Identifier Uniform Resource Identifier https://ejournal.upi.edu/index.php/ijost/article/view/64219
 
10. Identifier Digital Object Identifier (DOI) https://doi.org/10.17509/ijost.v9i1.64219
 
11. Source Title; vol., no. (year) Indonesian Journal of Science and Technology; Vol 9, No 1 (2024): IJOST: April 2024
 
12. Language English=en en
 
13. Relation Supp. Files
 
14. Coverage Geo-spatial location, chronological period, research sample (gender, age, etc.)
 
15. Rights Copyright and permissions Copyright (c) 2023 Universitas Pendidikan Indonesia
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